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DX-CartridgeSafety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and RegulationsDate of issue: 01/28/2016Revision date: 01/28/2016Supersedes: 05/18/2015Version: 2.3SECTION 1: Identification1.1. IdentificationProduct formArticleNameDX-CartridgeProduct codeBU Direct Fastening1.2. Relevant identified uses of the substance or mixture and uses advised againstNo additional information available1.3. Details of the supplier of the safety data sheetSupplierHilti, Inc.Legacy Tower, Suite 100075024 Plano - USAT 1 97240358001-800-879-8000 toll free - F 1 918 254 0522Department issuing data specification sheetHilti Entwicklungsgesellschaft mbHHiltistrasse 686916 Kaufering - DeutschlandT 49 8191 906310 - F 49 8191 [email protected] Emergency telephone numberEmergency numberChem-TrecTel.: 1 800 424 9300 (USA, PR, Virgin Islands, Canada)Tel.: 703 527 3887 (Other countries) 1 918 87230001-800-879-8000 toll freeSECTION 2: Hazards identificationThe dismantling of the article is prohibited!,This article contains hazardous substances or preparations not intended to bereleased under normal or reasonably foreseeable conditions of use.2.1. Classification of the substance or mixtureGHS-US classificationExpl. 1.4H204 - Fire or projection hazardFull text of H-statements: see section 162.2. Label elementsGHS-US labellingHazard pictograms (GHS-US)GHS01Signal word (GHS-US)WarningHazard statements (GHS-US)H204 - Fire or projection hazardPrecautionary statements (GHS-US)P210 - Keep away from heat. - No smokingP250 - Do not subject to shockP280 - Wear eye protection2.3. Other hazardsNo additional information available17/02/2016EN (English)1/10

DX-CartridgeSafety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations2.4. Unknown acute toxicity (GHS US)Not applicableSECTION 3: Composition/information on ingredients3.1.SubstanceNot applicable3.2.MixtureNameProduct identifier%GHS-US classificationglycerol trinitrate(CAS No) 55-63-03 - 10Unst. Expl, H200Acute Tox. 2 (Oral), H300Acute Tox. 1 (Dermal), H310Acute Tox. 2 (Inhalation:dust,mist),H330STOT RE 2, H373Aquatic Chronic 2, H411lead styphnate(CAS No) 15245-44-00.1 - 5Unst. Expl, H200Acute Tox. 4 (Oral), H302Acute Tox. 4 (Inhalation:dust,mist),H332Repr. 1A, H360STOT RE 2, H373Aquatic Acute 1, H400Aquatic Chronic 1, H410Barium nitrate(CAS No) 10022-31-80-5Acute Tox. 4 (Oral), H302diphenylamine(CAS No) 122-39-40-1Acute Tox. 3 (Oral), H301Acute Tox. 3 (Dermal), H311Acute Tox. 3 (Inhalation:dust,mist),H331STOT RE 2, H373Aquatic Acute 1, H400Aquatic Chronic 1, H410Tetrazen(CAS No) 109-27-30 - 0.2Unst. Expl, H200Eye Irrit. 2A, H319Full text of H-statements: see section 16SECTION 4: First aid measures4.1. Description of first aid measuresFirst-aid measures after inhalationAllow breathing of fresh air. Allow the victim to rest.First-aid measures after skin contactRemove affected clothing and wash all exposed skin area with mild soap and water, followedby warm water rinse.First-aid measures after eye contactRinse immediately with plenty of water. Obtain medical attention if pain, blinking or rednesspersist.First-aid measures after ingestionRinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.4.2. Most important symptoms and effects, both acute and delayedSymptoms/injuriesNot expected to present a significant hazard under anticipated conditions of normal use.4.3. Indication of any immediate medical attention and special treatment neededNo additional information availableSECTION 5: Firefighting measures5.1. Extinguishing mediaSuitable extinguishing mediaFoam. Dry powder. Carbon dioxide. Water spray. Sand.Unsuitable extinguishing mediaDo not use a heavy water stream.5.2. Special hazards arising from the substance or mixtureNo additional information available17/02/2016EN (English)2/10

DX-CartridgeSafety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations5.3. Advice for firefightersFirefighting instructionsUse water spray or fog for cooling exposed containers. Exercise caution when fighting anychemical fire. Prevent fire-fighting water from entering environment.Protection during firefightingDo not enter fire area without proper protective equipment, including respiratory protection.SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresGeneral measuresRemove ignition sources. Use special care to avoid static electric charges. No open flames. Nosmoking.6.1.1. For non-emergency personnelEmergency proceduresEvacuate unnecessary personnel.6.1.2. For emergency respondersProtective equipmentEquip cleanup crew with proper protection.Emergency proceduresVentilate area.6.2. Environmental precautionsPrevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.6.3. Methods and material for containment and cleaning upMethods for cleaning upPick up loose cartridges only by hand.Exposed ingredients must be swept up carefully and phlegmatized in a water container,labelled according the regulations, wipe down with water the contamined area. Store away fromother materials.6.4. Reference to other sectionsFor further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13.SECTION 7: Handling and storage7.1. Precautions for safe handlingAdditional hazards when processedHazardous waste due to potential risk of explosion.Precautions for safe handlingDo not subject to grinding,shock, friction. Take precautionary measures against staticdischarge. Wash hands and other exposed areas with mild soap and water before eating,drinking or smoking and when leaving work.Hygiene measuresDo not eat, drink or smoke when using this product. Always wash hands after handling theproduct.7.2. Conditions for safe storage, including any incompatibilitiesStorage conditionsKeep only in the original container in a cool, well ventilated place away from : Direct sunlight,Heat sources. Store in a dry place.Incompatible productsStrong bases. Strong acids.Incompatible materialsSources of ignition. Direct sunlight.Storage temperature5 - 25 CProhibitions on mixed storageKEEP SUBSTANCE AWAY FROM: highly flammable materials. ignition sources.Storage areaStore away from heat.SECTION 8: Exposure controls/personal protection8.1. Control parameters17/02/2016EN (English)3/10

DX-CartridgeSafety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulationsglycerol trinitrate (55-63-0)ACGIHACGIH TWA (ppm)0.05 ppmACGIHACGIH STEL (ppm)0.05 ppmACGIHRemark (ACGIH)VasodilationOSHAOSHA PEL (Ceiling) (mg/m³)2 mg/m³OSHAOSHA PEL (Ceiling) (ppm)0.2 ppmBarium nitrate (10022-31-8)ACGIHACGIH TWA (mg/m³)0.5 mg/m³diphenylamine (122-39-4)ACGIHACGIH TWA (mg/m³)10 mg/m³ACGIHRemark (ACGIH)Liver & kidney dam; hematologic eff8.2. Exposure controlsPersonal protective equipmentAvoid all unnecessary exposure. Safety glasses. Protective clothing.Eye protectionSafety glasses.Skin and body protectionWhen using setting tools, sufficient ear protection must be worn.Other informationDo not eat, drink or smoke during use.SECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesPhysical stateSolidColourAccording to product specificationOdourThere may be no odour warning properties, odour is subjective and inadequate to warn ofoverexposure.Mixture contains one or more component(s) which have the following odour(s):No data available on odour Pleasant odour Floral odour OdourlessOdour thresholdNo data availablepHNo data availableMelting pointNo data availableFreezing pointNo data availableBoiling pointNo data availableFlash pointNo data availableRelative evaporation rate (butylacetate 1)No data availableFlammability (solid, gas)No data availableExplosive limitsNo data availableExplosive propertiesFire or projection hazard.Oxidising propertiesNo data availableVapour pressureNo data availableRelative densityNo data availableRelative vapour density at 20 CNo data availableSolubilityNo data availableLog PowNo data availableAuto-ignition temperatureNo data available17/02/2016EN (English)4/10

DX-CartridgeSafety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and RegulationsDecomposition temperatureNo data availableViscosityNo data availableViscosity, kinematicNo data availableViscosity, dynamicNo data available9.2. Other informationNo additional information availableSECTION 10: Stability and reactivity10.1. ReactivityNo additional information available10.2. Chemical stabilityStable under normal conditions.10.3. Possibility of hazardous reactionsNot established.10.4. Conditions to avoidDirect sunlight. Extremely high or low temperatures. Heat. Sparks. Open flame. Overheating.10.5. Incompatible materialsStrong acids. Strong bases.10.6. Hazardous decomposition productsfume. Carbon monoxide. Carbon dioxide. Nitrogen oxides.SECTION 11: Toxicological information11.1. Information on toxicological effectsAcute toxicityNot classifiedglycerol trinitrate (55-63-0)ATE US (oral)ATE US (dermal)ATE US (dust,mist)5.000 mg/kg bodyweight5.000 mg/kg bodyweight0.050 mg/l/4hBarium nitrate (10022-31-8)LD50 oral ratATE US (oral)355 mg/kg (Rat)355.000 mg/kg bodyweightlead styphnate (15245-44-0)ATE US (oral)ATE US (dust,mist)500.000 mg/kg bodyweight1.500 mg/l/4hdiphenylamine (122-39-4)ATE US (oral)ATE US (dermal)ATE US (dust,mist)100.000 mg/kg bodyweight300.000 mg/kg bodyweight0.500 mg/l/4hSkin corrosion/irritationNot classifiedSerious eye damage/irritationNot classifiedRespiratory or skin sensitisationNot classified17/02/2016EN (English)5/10

DX-CartridgeSafety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and RegulationsGerm cell mutagenicityNot classifiedBased on available data, the classification criteria are not metCarcinogenicityNot classifiedReproductive toxicityNot classifiedBased on available data, the classification criteria are not metSpecific target organ toxicity (single exposure)Not classifiedSpecific target organ toxicity (repeatedexposure)Not classifiedAspiration hazardNot classifiedPotential adverse human health effects andsymptomsBased on available data, the classification criteria are not met. No harmful effects are to beexpected if used properly.The contained ingredients can be harmful, but they are hermetically enclosed in the article andcan not be released.The dismantling of the article is prohibited.SECTION 12: Ecological information12.1. ToxicityEcology - generalNo harmful effects are to be expected if used properly.The contained ingredients can be harmful, but they are hermetically enclosed in the article andcan not be released.The dismantling of the article is prohibited.glycerol trinitrate (55-63-0)LC50 fish 1EC50 Daphnia 1LC50 fish 2ErC50 (algae)NOEC chronic fishThreshold limit algae 12.1 mg/l (96 h; Pimephales promelas)25 mg/l (168 h; Daphnia magna)1.3 mg/l (96 h; Lepomis macrochirus)0.4 mg/l0.03 mg/l 6.5 mg/l (Scenedesmus quadricauda)Barium nitrate (10022-31-8)LC50 fish 1LC50 other aquatic organisms 1Threshold limit other aquatic organisms 11900 mg/l 1000 mg/l (96 h) 1000 mg/l (96 h)lead styphnate (15245-44-0)EC50 Daphnia 1TLM fish 1Threshold limit algae 17 mg/l7.48 mg/l (96 h; Pimephales promelas; Lead ion)0.14 mg/l (Selenastrum capricornutum; Lead ion)diphenylamine (122-39-4)LC50 fish 1EC50 Daphnia 1LC50 fish 2ErC50 (algae)Threshold limit other aquatic organisms 1Threshold limit algae 1 20 mg/l (48 h; Leuciscus idus)2.3 mg/l (24 h; Daphnia magna)2.2 - 5.1 mg/l (48 h; Oryzias latipes)0.36 mg/l1000 mg/l (24 h; Pseudomonas fluorescens)0.048 mg/l (72 h; Scenedesmus subspicatus; Inhibitory)Tetrazen (109-27-3)EC50 Daphnia 10.14 mg/l17/02/2016EN (English)6/10

DX-CartridgeSafety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations12.2. Persistence and degradabilityDX-CartridgePersistence and degradabilityNot established.glycerol trinitrate (55-63-0)Persistence and degradabilityBiochemical oxygen demand (BOD)Biodegradable in water.Barium nitrate (10022-31-8)Persistence and degradabilityBiochemical oxygen demand (BOD)Biodegradability: not applicable.Chemical oxygen demand (COD)Not applicableThODNot applicableBOD (% of ThOD)Not applicablediphenylamine (122-39-4)Persistence and degradabilityThODNot readily biodegradable in water.53.6 g O₂/g substanceNot applicable2.39 g O₂/g substance12.3. Bioaccumulative potentialDX-CartridgeBioaccumulative potentialNot established.glycerol trinitrate (55-63-0)Log PowBioaccumulative potential1.62Low potential for bioaccumulation (Log Kow 4).Barium nitrate (10022-31-8)Bioaccumulative potentialNot bioaccumulative.diphenylamine (122-39-4)BCF fish 1Log PowBioaccumulative potential51 - 253 (Cyprinus carpio; Test duration: 8 weeks)3.22 - 3.50Low potential for bioaccumulation (BCF 500).12.4. Mobility in soildiphenylamine (122-39-4)Surface tensionEcology - soil0.03 N/m (60 C)May be harmful to plant growth, blooming and fruit formation.12.5. Other adverse effectsEffect on the global warmingNo known ecological damage caused by this product.Other informationAvoid release to the environment.SECTION 13: Disposal considerations13.1. Waste treatment methodsWaste disposal recommendationsDispose in a safe manner in accordance with local/national regulations. Refer tomanufacturer/supplier for information on recovery/recycling.Additional informationHazardous waste due to potential risk of explosion.Ecology - waste materialsAvoid release to the environment.17/02/2016EN (English)7/10

DX-CartridgeSafety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and RegulationsSECTION 14: Transport informationIn accordance with ADR / RID / IMDG / IATA / ADNADRIMDGIATARID032303230323Cartridges, power deviceCARTRIDGES, POWER DEVICE1.4S1.4S1.4SNot applicableNot applicableNot applicableDangerous for the environment :NoMarine pollutant : NoDangerous for the environment :NoDangerous for the environment :No14.1. UN number032314.2. UN proper shipping nameCARTRIDGES, POWER DEVICECARTRIDGES, POWER DEVICETransport document descriptionUN 0323 CARTRIDGES, POWERDEVICE (1.4S), (E)UN 0323 CARTRIDGES, POWERDEVICE, 1.4S14.3. Transport hazard class(es)1.4S14.4. Packing groupNot applicable14.5. Environmental hazardsDangerous for the environment :NoNo supplementary information available14.6. Special precautions for user- Overland transportSpecial provisions (ADR)347Limited quantities (ADR)0Packing instructions (ADR)P134, LP102Mixed packing provisions (ADR)MP23Tunnel restriction code (ADR)E- Transport by seaSpecial provisions (IMDG)347Limited quantities (IMDG)0Packing instructions (IMDG)P134, LP102EmS-No. (Fire)F-BEmS-No. (Spillage)S-XStowage category (IMDG)01Stowage and segregation (IMDG)Protected from sources of heatMFAG-No114- Air transportPCA packing instructions (IATA)134PCA max net quantity (IATA)25kgSpecial provisions (IATA)A16517/02/2016EN (English)8/10

DX-CartridgeSafety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations- Rail transportSpecial provisions (RID)347Limited quantities (RID)0Packing instructions (RID)P134, LP102Carriage prohibited (RID)No14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeSECTION 15: Regulatory information15.1. US Federal regulationsAll components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic SubstancesControl Act (TSCA) inventoryChemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of1986 and 40 CFR Part 372.glycerol trinitrateCAS No 55-63-03 - 10%diphenylamineCAS No 122-39-40 - 1%glycerol trinitrate (55-63-0)Subject to reporting requirements of United States SARA Section 313RQ (Reportable quantity, section 304 of EPA's10 lbList of Lists)diphenylamine (122-39-4)Subject to reporting requirements of United States SARA Section 313EPA TSCA Regulatory FlagT - T - indicates a substance that is the subject of a Section 4 test rule under TSCA.15.2. International regulationsCANADANo additional information availableEU-RegulationsNo additional information availableClassification according to Regulation (EC) No. 1272/2008 [CLP]Expl. 1.4 H204Full text of hazard classes and H-statements : see section 16National regulationsNo additional information available15.3. US State regulationsCalifornia Proposition 65 - This product does not contain any substances known to the state of California to causecancer, developmental and/or reproductive harmSECTION 16: Other informationRevision date17/02/201601/28/2016EN (English)9/10

DX-CartridgeSafety Data Sheetaccording to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and RegulationsFull text of H-statements:-----Acute Tox. 1 (Dermal)-----Acute Tox. 2 (Inhalation:dust,mist)-----Acute Tox. 2 (Oral)-----Acute Tox. 3 (Dermal)-----Acute Tox. 3 (Inhalation:dust,mist)-----Acute Tox. 3 (Oral)-----Acute Tox. 4 (Inhalation:dust,mist)-----Acute Tox. 4 (Oral)-----Aquatic Acute 1-----Aquatic Chronic 1------Aquatic Chronic ------------------------------------------Expl. 1.4Eye Irrit. 2ARepr. 1ASTOT RE 2Unst. 60H373----------------H400H410H411Acute toxicity (dermal), Category 1Acute toxicity (inhalation:dust,mist) Category 2Acute toxicity (oral), Category 2Acute toxicity (dermal), Category 3Acute toxicity (inhalation:dust,mist) Category 3Acute toxicity (oral), Category 3Acute toxicity (inhalation:dust,mist) Category 4Acute toxicity (oral), Category 4Hazardous to the aquatic environment — Acute Hazard, Category 1Hazardous to the aquatic environment — Chronic Hazard, Category1Hazardous to the aquatic environment — Chronic Hazard, Category2Explosives, Division 1.4Serious eye damage/eye irritation, Category 2AReproductive toxicity, Category 1ASpecific target organ toxicity — Repeated exposure, Category 2Explosives, Unstable explosivesUnstable explosivesFire or projection hazardFatal if swallowedToxic if swallowedHarmful if swallowedFatal in contact with skinToxic in contact with skinCauses serious eye irritationFatal if inhaledToxic if inhaledHarmful if inhaledMay damage fertility or the unborn childMay cause damage to organs through prolonged or repeatedexposureVery toxic to aquatic lifeVery toxic to aquatic life with long lasting effectsToxic to aquatic life with long lasting effectsSDS US HiltiThis information is based on our current knowledge and is intended to describe the product for the purposes of health, safety andenvironmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product17/02/2016EN (English)10/10

Jun 27, 2016 · Hilti, Inc. Legacy Tower, Suite 1000 75024 Plano - USA T 1 9724035800 1-800-879-8000 toll free - F 1 918 254 0522 Department issuing data specification sheet Hilti Entwicklungsgesellschaft mbH Hiltistrasse 6 86916 Kaufering - Deutschland T 49 8191 906310 - F 49 8191 90176310 [email protected]