SAFETY DATA SHEETOBERON1/9Revision Date: 09.10.2017Print Date: 08.12.2017Version 1 / NZ102000007775SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THECOMPANY/UNDERTAKING1.1 Product identifierTrade nameOBERONProduct code (UVP)055443001.2 Relevant identified uses of the substance or mixture and uses advised againstUseInsecticideEPA-Nr.HSR0076911.3 Details of the supplier of the safety data sheetSupplierBayer New Zealand Limited3 Argus Place, HillcrestAuckland 0627New ZealandTelephone0800 428 246Telefax(09) 441 86451.4 Emergency telephone no.Emergency Number0800 734 607 (24hr)Global Incident ResponseHotline (24h) 1 (760) 476-3964 (Company 3E for Bayer AG, Crop Science Division)SECTION 2: HAZARDS IDENTIFICATION2.1 Classification of the substance or mixtureClassified as hazardous according to the criteria in the Hazardous Substances (MinimumDegrees of Hazard) Regulations 20016.5BH317May cause an allergic skin reaction.6.9BH373May cause damage to organs through prolonged or repeated exposure.9.1AH410Very toxic to aquatic life with long lasting effects.2.2 Label elementsLabelling in accordance with Hazardous Substances Identification Regulations 2001Hazard label for supply/use required.
SAFETY DATA SHEETOBERON2/9Revision Date: 09.10.2017Print Date: 08.12.2017Version 1 / NZ102000007775Signal word: WarningHazard statementsH317H373H410May cause an allergic skin reaction.May cause damage to organs through prolonged or repeated exposure.Very toxic to aquatic life with long lasting effects.Precautionary statementsP260P308 P311P321P391P501Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.IF exposed or concerned: Call a POISON CENTER/ doctor/ physician.Specific treatment (see supplemental first aid instructions on this label).Collect spillage.Dispose of contents/container in accordance with local regulation.2.3 Other hazardsNo other hazards known.SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS3.2 MixturesChemical natureSuspension concentrate ( flowable concentrate)(SC)Spiromesifen 240g/lHazardous components
SAFETY DATA SHEETOBERON3/9Revision Date: 09.10.2017Print Date: 08.12.2017Version 1 / NZ102000007775InhalationMove to fresh air. Keep patient warm and at rest. Call a physician orpoison control center immediately.Skin contactWash off thoroughly with plenty of soap and water, if available withpolyethyleneglycol 400, subsequently rinse with water. If symptomspersist, call a physician.Eye contactRinse immediately with plenty of water, also under the eyelids, for atleast 15 minutes. Remove contact lenses, if present, after the first 5minutes, then continue rinsing eye. Get medical attention if irritationdevelops and persists.IngestionRinse mouth. Do NOT induce vomiting. Call a physician or poisoncontrol center immediately.4.2 Most important symptoms and effects, both acute and delayedSymptomsNo symptoms known or expected.4.3 Indication of any immediate medical attention and special treatment neededTreatmentTreat symptomatically. In case of ingestion gastric lavage should beconsidered in cases of significant ingestions only within the first 2hours. However, the application of activated charcoal and sodiumsulphate is always advisable. There is no specific antidote.Contact the National Poisons and Hazardous Chemicals Information center in Dunedin, PO Box 913,Dunedin. Phone 0800 POISON (0800 764 766).SECTION 5: FIREFIGHTING MEASURES5.1 Extinguishing mediaSuitableWater spray, Carbon dioxide (CO2), Foam, Sand5.2 Special hazards arisingfrom the substance ormixtureIn the event of fire the following may be released:, Carbon monoxide(CO)5.3 Advice for firefightersSpecial protectiveequipment for firefightersIn the event of fire and/or explosion do not breathe fumes. In the eventof fire, wear self-contained breathing apparatus.Further informationContain the spread of the fire-fighting media. Do not allow run-off fromfire fighting to enter drains or water courses.SECTION 6: ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency proceduresPrecautionsAvoid contact with spilled product or contaminated surfaces. Usepersonal protective equipment.
SAFETY DATA SHEETOBERON4/9Revision Date: 09.10.2017Print Date: 08.12.2017Version 1 / NZ1020000077756.2 EnvironmentalprecautionsDo not allow to get into surface water, drains and ground water.6.3 Methods and materials for containment and cleaning upMethods for cleaning upSoak up with inert absorbent material (e.g. sand, silica gel, acidbinder, universal binder, sawdust). Clean contaminated floors andobjects thoroughly, observing environmental regulations. Keep insuitable, closed containers for disposal.6.4 Reference to othersectionsInformation regarding safe handling, see section 7.Information regarding personal protective equipment, see section 8.Information regarding waste disposal, see section 13.SECTION 7: HANDLING AND STORAGE7.1 Precautions for safe handlingAdvice on safe handlingUse only in area provided with appropriate exhaust ventilation.Hygiene measuresAvoid contact with skin, eyes and clothing. Keep working clothesseparately. Wash hands immediately after work, if necessary take ashower. Remove soiled clothing immediately and clean thoroughlybefore using again. Garments that cannot be cleaned must bedestroyed (burnt).7.2 Conditions for safe storage, including any incompatibilitiesRequirements for storageareas and containersStore in original container. Keep containers tightly closed in a dry, cooland well-ventilated place. Store in a place accessible by authorizedpersons only. Keep away from direct sunlight.Advice on common storageKeep away from food, drink and animal feedingstuffs.Suitable materialsHDPE (high density polyethylene)7.3 Specific end use(s)Refer to the label and/or leaflet.SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control Glycerine56-81-5Control parameters0,92 mg/m3(SK-SEN)10 mg/m3(TWA)UpdateBasisOES BCS*06 2016NZ OEL(Mist.)*OES BCS: Internal Bayer AG, Crop Science Division "Occupational Exposure Standard"8.2 Exposure controlsPersonal protective equipmentIn normal use and handling conditions please refer to the label and/or leaflet. In all other cases thefollowing recommendations would apply.Respiratory protectionRespiratory protection is not required under anticipated
SAFETY DATA SHEETOBERON5/9Revision Date: 09.10.2017Print Date: 08.12.2017Version 1 / NZ102000007775circumstances of exposure.Respiratory protection should only be used to control residual risk ofshort duration activities, when all reasonably practicable steps havebeen taken to reduce exposure at source e.g. containment and/orlocal extract ventilation. Always follow respirator manufacturer'sinstructions regarding wearing and maintenance.Hand protectionPlease observe the instructions regarding permeability andbreakthrough time which are provided by the supplier of the gloves.Also take into consideration the specific local conditions under whichthe product is used, such as the danger of cuts, abrasion, and thecontact time.Wash gloves when contaminated. Dispose of when contaminatedinside, when perforated or when contamination on the outside cannotbe removed. Wash hands frequently and always before eating,drinking, smoking or using the toilet.MaterialNitrile rubberRate of permeability 480 minGlove thickness 0,4 mmDirectiveProtective gloves complying with EN374.Eye protectionWear goggles (conforming to EN166, Field of Use 5 or equivalent).Skin and body protectionWear standard coveralls and Category 3 Type 6 suit.If there is a risk of significant exposure, consider a higher protectivetype suit.Wear two layers of clothing wherever possible. Polyester/cotton orcotton overalls should be worn under chemical protection suit andshould be professionally laundered frequently.If chemical protection suit is splashed, sprayed or significantlycontaminated, decontaminate as far as possible, then carefullyremove and dispose of as advised by manufacturer.SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical propertiesFormsuspensionColourgrey whiteOdourweak, characteristicpH4,0 - 5,5 at 100 % (23 C)Flash point 100 CNo flash point - Determination conducted up to the boiling point.Ignition temperature410 CDensityca. 1,05 g/cm³ at 20 CWater solubilitymisciblePartition coefficient: noctanol/waterSpiromesifen: log Pow: 4,55 at 20 CImpact sensitivityNot impact sensitive.
SAFETY DATA SHEETOBERON6/9Revision Date: 09.10.2017Print Date: 08.12.2017Version 1 / NZ102000007775Oxidizing propertiesNo oxidizing propertiesExplosivityNot explosive92/69/EEC, A.14 / OECD 1139.2 Other informationFurther safety related physical-chemical data are not known.SECTION 10: STABILITY AND REACTIVITY10.1 ReactivityThermal decompositionStable under normal conditions.10.2 Chemical stabilityStable under recommended storage conditions.10.3 Possibility ofhazardous reactionsNo hazardous reactions when stored and handled according toprescribed instructions.10.4 Conditions to avoidExtremes of temperature and direct sunlight.10.5 Incompatible materialsStore only in the original container.10.6 Hazardousdecomposition productsNo decomposition products expected under normal conditions of use.SECTION 11: TOXICOLOGICAL INFORMATION11.1 Information on toxicological effectsAcute oral toxicityLD50 (Rat) 2.500 mg/kgAcute inhalation toxicityLC50 (Rat) 2,759 mg/lExposure time: 4 hDetermined in the form of a respirable aerosol.Highest attainable concentration.Acute dermal toxicityLD50 (Rat) 4.000 mg/kgSkin irritationNo skin irritation (Rabbit)Eye irritationNo eye irritation (Rabbit)SensitisationNon-sensitizing. (Guinea pig)OECD Test Guideline 406, Buehler testAssessment STOT Specific target organ toxicity – single exposureSpiromesifen: Based on available data, the classification criteria are not met.Assessment STOT Specific target organ toxicity – repeated exposureSpiromesifen did not cause specific target organ toxicity in experimental animal studies.Assessment mutagenicitySpiromesifen was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.Assessment carcinogenicity
SAFETY DATA SHEETOBERON7/9Revision Date: 09.10.2017Print Date: 08.12.2017Version 1 / NZ102000007775Spiromesifen was not carcinogenic in lifetime feeding studies in rats and mice.Assessment toxicity to reproductionSpiromesifen caused reproduction toxicity in a two-generation study in rats only at dose levels also toxicto the parent animals. The reproduction toxicity seen with Spiromesifen is related to parental toxicity.Assessment developmental toxicitySpiromesifen caused developmental toxicity only at dose levels toxic to the dams. The developmentaleffects seen with Spiromesifen are related to maternal toxicity.Aspiration hazardBased on available data, the classification criteria are not met.SECTION 12: ECOLOGICAL INFORMATION12.1 ToxicityToxicity to fishLC50 (Lepomis macrochirus (Bluegill sunfish)) 0,245 mg/lExposure time: 96 hToxicity to aquaticinvertebratesEC50 (Daphnia magna (Water flea)) 68,7 mg/lExposure time: 48 hToxicity to aquatic plantsIC50 (Raphidocelis subcapitata (freshwater green alga)) 6,4 mg/lGrowth rate; Exposure time: 72 h12.2 Persistence and degradabilityBiodegradabilitySpiromesifen:Not rapidly biodegradableKocSpiromesifen: Koc: 3090012.3 Bioaccumulative potentialBioaccumulationSpiromesifen: Bioconcentration factor (BCF) 545Does not bioaccumulate.12.4 Mobility in soilMobility in soilSpiromesifen: Immobile in soil12.5 Results of PBT and vPvB assessmentPBT and vPvB assessmentSpiromesifen: This substance is not considered to be persistent,bioaccumulative and toxic (PBT). This substance is not considered to bevery persistent and very bioaccumulative (vPvB).12.6 Other adverse effectsAdditional ecologicalinformationNo other effects to be mentioned.SECTION 13: DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
SAFETY DATA SHEETOBERON8/9Revision Date: 09.10.2017Print Date: 08.12.2017Version 1 / NZ102000007775ProductDispose of this product only by using according to the label, or at anapproved landfill or other approved facility.Contaminated packagingTriple rinse containers. Recycle if possible. If allowed under localauthority, burn if circumstances, especially wind direction permit,otherwise crush and bury in an approved local authority facility. Do notuse container for any other purpose.SECTION 14: TRANSPORT INFORMATIONThis transportation information is not intended to convey all specific regulatory information relating tothis product. It does not address regulatory variations due to package size or special transportationrequirements.ADR/RID/ADN14.1 UN number14.2 Proper shipping name14.3 Transport hazard class(es)14.4 Packing group14.5 Environm. Hazardous MarkHazchem CodeIMDG14.1 UN number14.2 Proper shipping name14.3 Transport hazard class(es)14.4 Packing group14.5 Marine pollutantIATA14.1 UN number14.2 Proper shipping name14.3 Transport hazard class(es)14.4 Packing group14.5 Environm. Hazardous Mark3082ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,N.O.S.(SPIROMESIFEN SOLUTION)9IIIYES3Z3082ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,N.O.S.(SPIROMESIFEN SOLUTION)9IIIYES3082ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,N.O.S.(SPIROMESIFEN SOLUTION )9IIIYES14.6 Special precautions for userSee sections 6 to 8 of this Safety Data Sheet.14.7 Transport in bulk according to Annex II of MARPOL and the IBC CodeNo transport in bulk according to the IBC Code.SECTION 15: REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance ormixture
SAFETY DATA SHEETOBERON9/9Revision Date: 09.10.2017Print Date: 08.12.2017Version 1 / NZ102000007775Further informationHSNO approval-Nr.HSNO ControlsACVM Reg.ACVM ConditionHSR007691See www.epa.govt.nzP7567See www.foodsafety.govt.nzSECTION 16: OTHER INFORMATIONAbbreviations and CDRIDTWAUNWHOEuropean Agreement concerning the International Carriage of Dangerous Goods byInland WaterwaysEuropean Agreement concerning the International Carriage of Dangerous Goods byRoadAcute toxicity estimateChemical Abstracts Service numberConcentrationEffective concentration to x %European inventory of existing commercial substancesEuropean list of notified chemical substancesEuropean StandardEuropean UnionInternational Air Transport AssociationInternational Code for the Construction and Equipment of Ships Carrying DangerousChemicals in Bulk (IBC Code)Inhibition concentration to x %International Maritime Dangerous GoodsLethal concentration to x %Lethal dose to x %Lowest observed effect concentration/levelMARPOL: International Convention for the prevention of marine pollution from shipsNot otherwise specifiedNo observed effect concentration/levelOrganization for Economic Co-operation and DevelopmentRegulations concerning the International Carriage of Dangerous Goods by RailTime weighted averageUnited NationsWorld health organisationThe data given here is based on current knowledge and experience. The purpose of this Safety DataSheet is to describe products in terms of their safety requirements. The above details do not implyany guarantee concerning composition, properties or performance of the product.Changes since the last version are highlighted in the margin. This version replaces all previousversions.
Trade name OBERON . Product code (UVP) 05544300 1.2 Relevant identified uses of the substance or mixture and uses advised against . Use Insecticide . EPA-Nr. HSR007691 1.3 Details of the supplier of the safety data sheet . Supplier Bayer New Zealand Limited 3 Argus P